Tracing sulfur sources in the crust via SIMS measurements of sulfur isotopes in apatite

نویسندگان

چکیده

We present a refined approach for acquiring sulfur (S) isotope compositions (33S/32S, 34S/32S) in apatite by secondary ion mass spectrometry (SIMS), including the characterisation of new reference materials. In order to test method, we analyzed potential samples their S ratios via three different bulk methods. The investigated contain concentrations between ~160 μg/g and 3100 34S/32S (δ34S) deviate more than 25‰ from Vienna-Canyon Diablo Troilite (VCDT) standard. identified four candidates as primary materials routine SIMS measurements apatite. Based on ICP-MS, EA-IRMS, fluorination analyses, recommended values are +12.27± 0.22 (2σ) ‰ δ34S SAP1, +14.02 ± Big1, −1.06 0.80 Durango-A, −1.39 0.48 Durango-B. By selecting one those standards analysis, other additional tested specimens can be reproduced within 1‰. Under optimized conditions, single spot uncertainty that combines within-spot precision repeatability material during an analytical session is ±0.4‰ (95% CI). also show with > 1000 μg/g, analysis permits detection mass-independent signatures (i.e., Δ33S) larger ~1.0‰ if average multiple grains used, ~1.5‰ point. Furthermore, our study shows record extremely diverse environments, making this near-ubiquitous mineral key candidate tracing source reservoirs track pathway magmatic-hydrothermal fluids wide range geological settings.

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ژورنال

عنوان ژورنال: Chemical Geology

سال: 2021

ISSN: ['0009-2541', '1872-6836']

DOI: https://doi.org/10.1016/j.chemgeo.2021.120242